Accidental release measures Special hazards arising from the substance or mixture If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide Sulfur oxides (SOx) ... Potassium Thiocyanate (Potassium Rhodanide) is generally immediately available in most volumes. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 7757-79-1 Potassium nitrate >99 231-818-8 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: white. Potassium Permanganate being conveyed through propylene tube ignited the tube. Product: Potassium Thiocyanate Revision Date: 07/17/2013 3/7 Special Protective Equipment As in any fire, wear MSHA/NIOSH approved (or equivalent) self-contained positive pressure Strong oxidizer. 333-20-0 3 Effective date : 12.16.2014 Page 2 of 7 Sodium Thiocyanate, Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Potassium Thiocyanate 333-20-0 90 - 100% Yes 3. : 333-20-0 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 1.3 Details of the supplier of the safety data sheet Contact with other material may cause a fire. View information & documentation regarding Potassium thiocyanate, including CAS, MSDS & more. Hazard Identification Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation (lung ACCIDENTAL RELEASE MEASURES CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Human oral LDLo: 80 mg/kg, hallucinations, distorted perceptions, convulsions, muscle weakness. Potassium thiocyanate Revision Date Oct-2018 SECTION 2: HAZARDS IDENTIFICATION For the full text of the R-phrases and H-Statements mentioned in this Section, see Section 16 2.2. 7732-18-5 Revision Date Potassium thiocyanate 333-20-0 1989-12-01 New Jersey Right To Know Components Water CAS-No. Potassium Thiocyanate 1. Special hazards arising from the substance or mixture No additional information available 5.3. Potassium thiocyanate is the chemical compound with the molecular formula KSCN. * Eye wash fountains should be provided in the immediate work area for emergency use. POTASSIUM page 2 of 6 This Fact Sheet is a summary source of information of all potential and most severe health hazards that may result from exposure. OSHA. May cause mild irritation to the skin and eyes. It is a pseudohalide anion and a sulfur molecular entity. Potassium Thiocyanate 333-20-0 < 0.2 Not Available Not Available Not Available Not Available Water, Deionized 7732-18-5 Balance Not Available Not Available Not Available Not Available Section 3: Hazard Identification Emergency Overview: Non-flammable, non-toxic, non-corrosive. ... individuals who have been informed of the hazards of exposure to Potassium Permanganate. Structure, properties, spectra, suppliers and links for: potassium ferrocyanide. Symptoms may include coughing, shortness of breath. Special Remarks on Fire Hazards: Spontaneously flammable on contact with ethylene glycol. Wear full protective equipment, including suitable respiratory protection. Potassium permanganate decomposes hydrogen Pennsylvania Right To Know Components Water CAS-No. Hazardous combustion products: Hydrogen cyanide. The probable lethal dose is … 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA Rabbit oral LDLo: … The story of the thiocyanates began in 1903 with Pauli, who suggested the use of potassium thiocyanate as a hypotensive agent. Contains: Potassium thiocyanate 2.3 Other hazards. 594 mg/kg [Mouse]. Skin: May cause skin irritation. Product Description: Potassium thiocyanate Cat No. Potential Health Effects Eye: May cause eye irritation. Chemical Product and Company information. Ph Eur Page 2 of 13 The life science business of Merck operates as MilliporeSigma in the US and Canada Acute toxicity, Category 4, Oral, H302 Acute toxicity, Category 4, Inhalation, H332 Acute toxicity, Category 4, Dermal, H312 Serious eye damage, Category 1, H318 In recent years thiocyanates have been used enthusiastically. 1. This is an example of a custom, not too rare, of reviving and injecting new enthusiasm into ancient discarded treatments. Sigma-Aldrich offers a number of Potassium thiocyanate products. : P/7280/50, P/7280/53 Synonyms Potassium rhodanide CAS-No 333-20-0 EC-No. Target Organs: Heart, brain. Specific Hazards: Thermal decomposition of potassium thiocyanate may produce toxic hydrogen cyanide fumes. Hygroscopic Hazards Identification. Uses advised against No Information available 1.3. Danger! 6. May be harmful if swallowed. When solid hydroxylamine is brought into contact with solid potassium permanganate, there is produced immediately a with flame. Label elements Signal Word Warning Hazard Statements H412 - Harmful to aquatic life with long lasting effects Duration of … Pennsylvania Right To Know Components Potassium thiocyanate CAS-No. ECOLOGICAL INFORMATION 12.1 Toxicity no data available 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential Thiocyanate is a pseudohalide anion obtained by deprotonation of the thiol group of thiocyanic acid. 206-370-1 Molecular Formula C K N S 1.2. Product name Potassium thiocyanate for analysis EMSURE® ACS,ISO,Reag. 3. The compound has a low melting point relative to most other inorganic salts. Product Identification Synonyms: Potassium sulfocyanate; Potassium thiocyanide; Thiocyanic acid, potassium salt; Potassium isothiocyanate CAS No. ... potassium thiocyanate Potassium thiocyanate 2.6 mg/m3 28 mg/m3 170 mg/m3 Ingredient Original IDLH Revised IDLH potassium thiocyanate Not Available Not Available Exposure controls Appropriate engineering It is an important salt of the thiocyanate anion , one of the pseudohalides . Appropriate Engineering controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of use or handling. May cause kidney damage. Ingestion: May cause psychosis, vomiting, disorientation, weakness, low blood pressure, convulsions and death which may be delayed. Special hazards arising from the substance or mixture If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide Sulfur oxides (SOx) Nitrogen oxides (NOx) Potassium oxide Advice for firefighters Protective equipment: Wear self-contained respirator. 110760-Potassium thiocyanate, ACS Version: 3 Revision date: 19/04/2016 Page 2 of 8 Print date: 19/04/2016 -Continued on next page.- P362+P364 Take off contaminated clothing and wash it before reuse. Product name : Potassium Thiocyanate CAS-No. Inhalation: Causes irritation to the respiratory tract. Wear fully protective impervious suit. Special controls should be in place for highly toxic chemicals or when significant skin, eye, or breathing exposures are possible. High purity, submicron and nanopowder forms may be considered. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. It has a role as a human metabolite. Special hazards arising from the substance or mixture No additional information available 5.3. I'm concerned about the information that KSCN can be used to resemble fake blood and stigmata; this may encourage some readers of the article to try this on their own hands and skins, yet the article doesn't mention any of the health risks, although the word "harmful" does appear. Potassium thiocyanate 333-20-0 100 Toxicological Data on Ingredients: Potassium thiocyanate: ORAL (LD50): Acute: 854 mg/kg [Rat]. Hazards Identification Emergency Overview-----WARNING! HARMFUL IF SWALLOWED OR INHALED. It has a role as a human metabolite. SECTION 6. Section 3: Hazards Identification Potential Acute Health Effects: Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation (lung irritant). Potassium Thiocyanate Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier:Potassium thiocyanate ... 5.2 Special hazards arising from the substance or mixture: 333-20-0 Revision Date 1989-12-01 New Jersey Right To Know Components Potassium thiocyanate CAS-No. Product name : Potassium thiocyanate Product Number : 207799 Brand : Sigma-Aldrich Index-No. Caution! 333-20-0 Potassium Thiocyanate <1.0 % 206-370-1 Hazard Symbols: XN Risk Phrases: 21/22 32 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: clear, colorless liquid. : 615-030-00-5 CAS-No. Unusual fire and explosions hazards Emits toxic fumes under fire conditions. Section 6. The reaction of phenylazoalkenes 424 with an excess of potassium thiocyanate in acetic acid produces the cycloadducts 425 that undergo further [3+2]-cycloaddition reaction with thiocyanic acid at the azomethine imine function giving rise to the bicyclic product imidazo[1,5-b][triazole]-2,5-dithiones 41 (Equation 87) <1998SL786>. 7732-18-5 Revision Date Health Hazards! 4.3 Indication of any immediate medical attention and special treatment needed No data available SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Dry powder 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx), Sulphur oxides, Potassium oxides 5.3 Advice for firefighters SARA 311/312 Hazards No SARA Hazards Massachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act. EUH statements: EUH032 Contact with acids liberates very toxic gas. May cause eye, skin, and respiratory tract irritation. Data on potassium thiocyanate, a very similar chemical: Human oral TDLo: 428 mg/kg, toxic psychosis, hallucinations, distorted perceptions, gastritis. Product name: Potassium Thiocyanate Contact Information: Radchem cc PO Box 166982 Brackendowns Alberton 1454 Telephone : 011 867 3726 / 2864 2. Potassium Thiocyanate,ACS Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com Control Parameters: 333 - 20 - 0, Potassium thiocyanate, TWA 5 mg/m3 USA. May cause methemoglobinemia. SARA 311/312 Hazards Acute Health Hazard, Chronic Health Hazard Massachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act. 5.2 Special hazards arising from the substance or mixture ... Stomach - Irregularities - Based on Human Evidence (Potassium thiocyanate) 12. May cause irritation. POTASSIUM THIOCYANATE Prepared 05/12/01 By Dr. B. Dunlevy Page 2 of 4 Special fire fighting procedures Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. : 333-20-0 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. Special hazards arising from the substrate or mixture Fire Incompatibility None known. Special Equipment and Precautions: Use water to cool nearby containers and structures. SAF-T-DATA(tm) Ratings (Provided here ... Special Information: ( LD50 ): Acute: 854 mg/kg [ Rat ] Synonyms: thiocyanate... Hygroscopic thiocyanate is the chemical compound with the molecular formula KSCN hazards of exposure to Potassium Permanganate, is... On fire hazards: Thermal decomposition of Potassium thiocyanate: ORAL ( )! Potassium nitrate > 99 231-818-8 Section 3 - hazards Identification Emergency OVERVIEW special hazards of potassium thiocyanate: white it is important. 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